Envíe este artículo por correo electrónico Polihidruros de cobre: una poderosa herramienta en síntesis química. El reactivo de Stryker en perspectiva
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https://doi.org/10.53766/AVANQUIM/2021.16.02.01
El reactivo de Stryker, octaedro-hexa-µ3-hidrohexaquis(trifenilfosfina-?P)hexacobre(I), [(Ph3P)CuH)]6, reportado por el Grupo de Osborn en 1971, y sistemáticamente estudiado en sus aplicaciones químicas desde 1988 por Jeffrey M. Stry-ker, constituye una poderosa herramienta en la síntesis química de sustancias que tienen alto valor para la química fina. Desde sustancias con propiedades farmacológicas hasta llegar a compuestos de interés en catálisis, agroquímica, ciencia de materiales o nanoquímica, el reactivo de Stryker, catalogado en 1991 como “reactivo del año”, y todos sus polihidru-ros análogos, ofrecen grandes oportunidades para desarrollar protocolos de síntesis one-pot basados en una gran varie-dad de fosfinas quirales sintetizadas en las últimas décadas. A partir de los resultados obtenidos en la revisión que se ha realizado, se puede concluir que el reactivo de Stryker ha dado impulso a la investigación de cúmulos polihidruros de cobre(I) de alta nuclearidad, brindando nuevas oportunidades de investigación en síntesis orgánica y asimétrica o en el campo de la química inorgánica y organometálica.
Recibido: 05/08/2020
Aceptado: 20/08/2021
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