Síntesis y caracterización de hidrazonas obtenidas a partir de 1,2 y 1,4-naftoquinona con 2,4-dinitrofenilhidracina

Jesús R. Barrios, Marietta Vizcaya, Freddy A. Carrillo, Gerzon Delgado

Resumen


En este trabajo, se presentan los resultados de la síntesis en solución alcohólicay la caracterización de los derivados hidra-zonas de1,2 y 1,4-naftoquinonacon 2,4-dinitrofenilhidracina. Los productos [1] y [2] se caracterizaron por espectroscopía FT-IR, UV-visible, 1H-RMN y por difracción de rayos-X en muestras policristalinas. Los análisis espectroscópicos indican la formación de las hidrazonas esperadas. El estudio de difracción de rayos-X indica que ambas hidrazonas cristalizan en celdas monoclínicas con grupo espacial P21/c y parámetros de celda unidad: a=16,3541(7) Å, b=12,8648(6) Å, c =6,9195(1) Å, ß =100,140(2)°, V=1433,08(9) Å3y a =7,3274(2) Å, b =16,3523(7) Å, c =11,1187(5), ß =99,266(4)°, V=1314,86(9) Å3, para los derivados[1] y [2], respectivamente.

Recibido: 30/04/2021
Revisado: 08/07/2021
Aceptado: 12/08/2021


Palabras clave


hidrazona; síntesis química; 1,2-naftoquinona; 1,4- naftoquinona; 2,4-nitrofenilhidracina

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Referencias


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